- Waldoboro (Population: 4,916)
- Wales (Population: 1,322)
- Warren (Population: 3,794)
- Washburn (Population: 1,627)
- Washington (Population: 1,345)
- Waterboro (Population: 6,214)
- Waterford (Population: 1,455)
- Waterville (Population: 15,605)
- Wayne (Population: 1,112)
- Wells (Population: 9,400)
- West Bath (Population: 1,798)
- West Gardiner (Population: 2,902)
- West Paris (Population: 1,722)
- Westbrook (Population: 16,142)
- Whitefield (Population: 2,273)
- Wilton (Population: 4,123)
- Windham (Population: 14,904)
- Windsor (Population: 2,204)
- Winslow (Population: 7,743)
- Winterport (Population: 3,602)
- Winthrop (Population: 6,232)
- Wiscasset (Population: 3,603)
- Woodland (Population: 1,403)
- Woodstock (Population: 1,307)
- Woolwich (Population: 2,810)
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